Experimental methods in chemical engineering: X-ray absorption spectroscopy—XAS,XANES, EXAFS

Although X-ray absorption spectroscopy (XAS) was conceived in the early 20th century, it took 60 years after the advent of synchrotrons for researchers to exploit its tremendous potential. Counterintuitively, researchers are now developing bench type polychromatic X-ray sources that are less brilliant to measure catalyst stability and work with toxic substances. XAS measures the absorption spectra of electrons that X-rays eject from the tightly bound core electrons to the continuum. The spectrum from 10 to 150 eV (kinetic energy of the photoelectrons) above the chemical potential—binding energy of core electrons—identifies oxidation state and band occupancy (X-ray absorption near edge structure, XANES), while higher energies in the spectrum relate to local atomic structure like coordination number and distance, Debye-Waller factor, and inner potential correction (extended X-ray absorption fine structure, EXAFS). Combining XAS with complementary spectroscopic techniques like Raman, Fourier transform infrared (FTIR), X-ray photoelectron spectroscopy (XPS), and electron paramagnetic resonance (EPR) elucidates the nature of the chemical bonds at the catalyst surface to better understand reaction mechanisms and intermediates. Because synchrotrons continue to be the light source of choice for most researchers, the number of articles Web of Science indexes per year has grown from 1000 in 1991 to 1700 in 2020. Material scientists and physical chemists publish an order of magnitude articles more than chemical engineers. Based on a bibliometric analysis, the research comprises five clusters centred around: electronic and optical properties, oxidation and hydrogenation catalysis, complementary analytical techniques like FTIR, nanoparticles and electrocatalysis, and iron, metals, and complexes.     

Estimation of Limit Energy Characteristics of Volumetric Pneumatic Motors Taking into Account the Process Dynamics in Working Chambers

A methodology for estimation of the limit energy characteristics of volumetric pneumatic motors based on the Parameter Space Investigation method and a generalized mathematical model in dimensionless (normalized) form taking into account the dynamics of working processes is proposed. A calculated example is presented. The methodology is applicable for determination of the limit energy characteristics of newly created design solutions, of prospects to improve the known designs of pneumatic motors, of evaluation of energy capacity of several pneumatic motors supplied from a single source of compressed air, and of the initial data preparation for parametric synthesis of rotational pneumatic drives for two or more robots taking into account their interaction.     

Distribution of Magnetic Flux in a Ferromagnetic Material in the Presence of a Nonferromagnetic Gap in the Composite Circuit

Russian Journal of Nondestructive Testing - Comparative analysis of the distribution of magnetic-induction vector components over the volume of a bulk homogeneous sample of 40Kh steel has been...     

Multilayer Partially Homomorphic Encryption Text Steganography (MLPHE-TS): A Zero Steganography Approach

Wireless Personal Communications - This paper presents a Multilayer Partially Homomorphic Encryption Text Steganography, an invisible approach for covert communication. Existing text-based schemes...     

Dynamics of Changes in the Photoluminescence of Porous Silicon after Gamma Irradiation

Radiation stability of the nanoporous silicon under gamma irradiation was investigated. Changes in the properties of porous silicon under gamma irradiation were registered by measurements of photoluminescence spectra and Fourier-transform infrared (FTIR) spectroscopy. Besides the appearance of point defects and their subsequent oxidation, the significant differences were shown to be in the behavior of the porous silicon properties in comparison with that of bulk silicon apparently due to the quantum size nature of nanoporous silicon.     

Hydrogen production by hybrid system and its conversion by fuel cell in Algeria; Djanet

In this work we present a scenario of wind and solar energy production and seasonal energy storage producing Hydrogen in Djanet (East-South of Algeria). In addition we suppose assume the use of a set of fuel cells which are connected to the grid to provide a supply of energy when needed afterwards. The aim of this primary study is giving an alternative solution for the electric production in Djanet, which is mainly based on diesel generator. For that we made an investigation to highlight the potential of renewable energy production in this region. To ascertain feasibility of one hybrid system, we made energetic assessment considering the real climatic conditions of Djanet.